The production of fine filaments of the normal ‘atomised’ particles when some solutions of certain classes of high polymers are sprayed. It may be reduced to a minimum, and often virtually eliminated, by careful selection of solvents and proper adjustment of spraying conditions. Although cobwebbing is generally considered a defect in ordinary lacquers, use is made of this property to provide a protective coating for equipment such as aeroplane engines. A cocoon is formed around the article by the pronounced cobwebbing action of lacquers specially prepared from certain high polymers. A durable, true film-forming lacquer is then sprayed over the cocoon which acts as a support.